Water boils at 100 degrees Celsius. From experience (hot springs in Japan), 37 is just right and anything above, 42 for example, and it feels like one is slowly cooking.
Given bodies are almost all water, we could easily be boiled away.
You could wipe out most of Earth’s population if it was so hot that all the water boiled away. That would kill almost everything on Earth… but maybe not the extremophiles. Extremophiles are awesome organisms that can survive in really extreme conditions.
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